Author Type

Graduate Student

Date of Award

1990

Document Type

Thesis

Publication Status

Version of Record

Submission Date

October 2026

Thesis/Dissertation Advisor [Chair]

Hartt, William H.

Abstract

Experiments were developed and performed to determine if glass electrodes can be employed to accurately measure pH of porewater in concrete. An attempt was made to determine the reason for the general underestimation of the alkalinity of porewater by one or more pH units when glass electrodes are used as sensors compared to the OH- concentration obtained from titration of pore solutions expressed from hydrated cement samples. The linear response and alkaline error of glass electrodes was investigated. pH was measured for mortar samples cast in air as well as under CO2-free conditions. A flat-surface combination electrode was mostly employed for this purpose, but studies also involved the use of a microelectrode. The possible role played by Ca(OH)2 liberated during cement hydration in decarbonation of porewater is discussed based on experiments.

Extent

92 p.

Comments

College of Engineering and Computer Science|FAU Electronic Theses and Dissertations Collection|Thesis (M.S.E.)--Florida Atlantic University, 1990.|College of Engineering and Computer Science

Identifier

FADT14649

Format

pdf

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