Author Type

Graduate Student

Date of Award

1991

Document Type

Thesis

Publication Status

Version of Record

Submission Date

October 2026

Thesis/Dissertation Advisor [Chair]

Lipka, Stephen M.

Abstract

An automated procedure for integrated cycling and electrochemical impedance spectroscopy (EIS) testing of nickel sinter individualized pressure vessel electrodes for secondary nickel/hydrogen batteries was developed. Nickel electrodes from three major U.S. manufacturers were cycled under various conditions. The condition of the electrodes was monitored using both EIS and traditional electrochemical methods. In order to establish relationships between the status of the electrodes and the acquired impedance spectra, various cycling and electrode parameters were analyzed and compared with the EIS data. Nonlinear least squares (NLS) regression was used for analysis of the impedance data. An equivalent circuit was developed which produced good correlation with the impedance data at all states-of-charge and discharge rates. Problems with the experimental procedure which limit the validity of EIS testing were discussed.

Extent

156 p.

Comments

College of Engineering and Computer Science|FAU Electronic Theses and Dissertations Collection|Thesis (M.S.E.)--Florida Atlantic University, 1991.|College of Engineering and Computer Science

Identifier

FADT14777

Format

pdf

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