Author

Author Type

Graduate Student

Date of Award

1997

Document Type

Thesis

Publication Status

Version of Record

Submission Date

October 2026

Thesis/Dissertation Advisor [Chair]

Medina, Fernando D.

Abstract

Zn1-x is a ternary alloy belonging to a class of materials known as Diluted Magnetic Semiconductors (DMS's). Single-crystal samples of this material possesses a cubic (zinc-blende) structure for x<0.30 and a hexagonal (wurtzite) structure for 0.30 300 K. Three emission bands are detected and are named the YEL (centered ~2.12 eV), ORA (centered 1.91 --> 1.98 eV) and IR bands. The shift of the YEL band is observed and related to the d-d interaction of the Mn^+2 ions and to thermal lattice expansion. The electron-phonon interaction is used to explain the broadening of the YEL band. A model is proposed to explain the existence of the ORA band and the shift of its energy with temperature and Mn concentration. This model for the first time provides a detailed explanation of the anomalous behavior of the energy gap of this material for low Mn concentrations.

Extent

129 p.

Comments

Thesis (M.S.)--Florida Atlantic University, 1997.|Thesis (M.S.)--Florida Atlantic University, 1997.

Identifier

FADT15388

Format

pdf

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