Author Type

Graduate Student

Date of Award

1989

Document Type

Thesis

Publication Status

Version of Record

Submission Date

October 2026

Thesis/Dissertation Advisor [Chair]

Smith, Samuel W.

Abstract

Formation of calcareous deposits on marine structures under cathodic protection reduces the current required to protect the surface, as time progresses. Computer aided design methods to date rely heavily on polarization data obtained from laborious and expensive in situ experiments. The present approach lays the foundation for a new design method in which the formation of calcareous deposits is modeled from first principles, based on precipitation and diffusion of ions of the constituent compounds in the boundary layer. Calcareous deposition in a one dimensional boundary layer was modeled and this model was used successfully to simulate the cathodic protection of a rotating cylinder in artificial sea water. Precipitation rate constant of Mg(OH)$\sb2$ was determined and the pH on the cylinder surface was estimated to be one tenth of a pH unit higher than that required for the precipitation of magnesium hydroxide from sea water.

Extent

117 p.

Comments

College of Engineering and Computer Science|FAU Electronic Theses and Dissertations Collection|Thesis (M.S.E.)--Florida Atlantic University, 1989.|College of Engineering and Computer Science

Identifier

FADT14495

Format

pdf

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