POLARIZED SINGLE CRYSTAL SPECTRA OF QUADRATE NICKEL(II) COMPLEXES

Author

• JAY STEUART MERRIAM

Author Type

Graduate Student

Date of Award

1972

Document Type

Thesis

Publication Status

Version of Record

Submission Date

October 2026

Abstract

The polarized single crystal spectra have been measured for quadrate nickel(II) complexes of the general formula [NiX4Y2] where X = pyridine and Y = Cl-, Br-, H2O. The unpolarized crystal spectrum is also reported where X = imidazole and Y = H2O. The tetragonally split components of the first and second cubic bands have been definitely assigned using polarization selection rules. Further transitions have been assigned from calculations of the energy levels including complete configurational interaction and spin-orbit coupling. The ligand field parameters and electron correlation parameters have been evaluated for each complex.

Extent

55 p.

Comments

Thesis (M.S.)--Florida Atlantic University, 1972.|Thesis (M.S.)--Florida Atlantic University, 1972.

Recommended Citation

MERRIAM, JAY STEUART, "POLARIZED SINGLE CRYSTAL SPECTRA OF QUADRATE NICKEL(II) COMPLEXES" (1972). Electronic Theses and Dissertations 1970 - 1979. 132.
https://digitalcommons.fau.edu/etd_general_2/132

Identifier

FADT13548

Format

pdf